Міжнародні видання
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Browsing Міжнародні видання by Subject "extrathermodynamics"
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Item Extrathermodynamics: Varieties of Compensation Effect(ACS, 2016-03-07) Ромашко, Таміла ПетрівнаThere are several types of the H compensation. Along with well-known phenomenon of the H-S compensation, two more types of the H-(S+Rln) compensation are observed in some series of systems. The nature of these phenomena is connected with the behavior of phase volume of systems, . The role of other thermodynamic parameters, which describe series, in manifestation of this or that types of the H compensation is shown in light of molecular statistical mechanics.Item One More Type of Extrathermodynamic Relationship(ACS, 2007-06) Ромашко, Таміла ПетрівнаA new type of extrathermodynamic relationship is presented: ¢H ) Ti[¢S + R ¢(ln ¿)] + â, where ¿ is the phase volume and â is a constant. This type of relationship holds for a series of systems in the case where ä¢(ln ¿) is changeable. The relation between this type of correlation and linear free-energy relationships is shown. An example of the specified correlation for energy parameters of excimers forming in different dipyrenylalkanes is demonstrated.Item The origin of extrathermodynamic compensations(2019-06) Хахель, Олег Альбінович; Ромашко, Таміла Петрівна